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The Macrolidic Glycolipid Calonyctin A, a Plant Growth Regulator: Synthesis, Structural Assignment, and Conformational Analysis in Micellar Solution
Author(s) -
Jiang ZiHua,
Geyer Armin,
Schmidt Richard R.
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199525201
Subject(s) - glycolipid , chemistry , amphiphile , nuclear magnetic resonance spectroscopy , turbidimetry , tetrasaccharide , stereochemistry , organic chemistry , chromatography , biochemistry , polysaccharide , copolymer , polymer
A tetrasaccharide, nilic acid, and jalapinolic acid served as building blocks in the total synthesis of calonyctin A ( 1 ) ( n = 1, 2). The conformation of this amphiphilic glycolipid was studied in micellar solution by NMR spectroscopy and molecuar dynamics simulation.