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Octaphyrin‐(1.0.1.0.1.0.1.0)
Author(s) -
Bröring Martin,
Jendrny Jörg,
Zander Lars,
Schmickler Hans,
Lex Johann,
Wu YunDong,
Nendel Maja,
Chen Jiangang,
Plattner Dietmar A.,
Houk Kendall N.,
Vogel Emanuel
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199525151
Subject(s) - pyrrole , porphyrin , derivative (finance) , solid state , condensation , chemistry , product (mathematics) , combinatorial chemistry , stereochemistry , photochemistry , physics , organic chemistry , mathematics , business , thermodynamics , geometry , finance
The formal exchange of the pyrrole units of porphyrin by bipyrrole units provides the title compound 1 . The hexadecaethyl derivative of 1 is the only isolable product of a MacDonald condensation of tetrapyrrolic as well as of dipyrrolic components. The new cyclooctapyrrole adopts a figure‐eight conformation in the solid state as well as in solution.