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Reactions of Neopentyl 2,2,2,‐Trifluoroethanesulfonate (Tresylate) with Nucleophiles: A Model Study for the Coupling of Nucleophiles with Tresyl Agarose
Author(s) -
Jennissen Herbert P.
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199524951
Subject(s) - nucleophile , homogeneous , reactivity (psychology) , chemistry , agarose , coupling (piping) , medicinal chemistry , organic chemistry , materials science , physics , thermodynamics , catalysis , chromatography , medicine , alternative medicine , pathology , metallurgy
Is it prudent to compare homogeneous and heterogeneous phase reactions? One side of this discussion on the reactivity of certain tresylates to nucleophiles such as butylamine and butanethiol says “Yes”, but the other says “Not always”.