[{Ti(μ‐CH 3 ) 5 (μ‐CH 2 )}{(tmeda)Li} 3 ] · THF: An Unusual and Highly Fluxional Titanium Organometallic Compound | Zendy

Berno Pietro | Zendy; Jenkins Hilary | Zendy; Gambarotta Sandro | Zendy; Blixt Johan | Zendy; Facey Glenn A. | Zendy; Detellier Christian | Zendy

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[{Ti(μ‐CH 3 ) 5 (μ‐CH 2 )}{(tmeda)Li} 3 ] · THF: An Unusual and Highly Fluxional Titanium Organometallic Compound

Author(s) -

Berno Pietro,

Jenkins Hilary,

Gambarotta Sandro,

Blixt Johan,

Facey Glenn A.,

Detellier Christian

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199522641

Subject(s) - methylene , titanium , group 2 organometallic chemistry , atom (system on chip) , chemistry , crystallography , medicinal chemistry , molecule , organic chemistry , computer science , embedded system

One methylene and five methyl groups are surprisingly the ligands attached to the titanium atom in 1 . Compound 1 is formed from the reaction of [{(Me 3 Si) 2 N} 3 Ti] with an excess of (Me 3 Si) 2 NLi followed by subsequent treatment with CH 2 Cl 2 . Unusual Ti‐H‐C bridges are present in the highly fluxional compound. Whether the methylene group in 1 stems from the solvent or not is still unclear.

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