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C 59 N + and C 69 N + : Isoelectronic Heteroanalogues of C 60 and C 70
Author(s) -
Lamparth Iris,
Nuber Berthold,
Schick Georg,
Skiebe Andreas,
Grösser Thomas,
Hirsch Andreas
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199522571
Subject(s) - fragmentation (computing) , nitrogen , ion , fullerene , nitrogen atom , chemistry , atom (system on chip) , atomic physics , carbon atom , mass spectrometry , carbon fibers , analytical chemistry (journal) , physics , materials science , ring (chemistry) , organic chemistry , chromatography , composite number , computer science , composite material , embedded system , operating system
Fragmentation reactions in the mass spectrometer were used to generate the first characterized nitrogen heterofullerene ions C 59 N + and C 69 N + from regioselectively synthesized oligoiminofullerenes. During this process one carbon atom in the fullerene core is removed and replaced with a nitrogen atom. C 59 N + (shown on the right) has almost the same structure as the isoelectronic C 60 .