A Novel Hexanuclear Fe III ‐ cis ‐Inositolato Complex as a Model for Fe III –Polyol Interactions in Aqueous Solution | Zendy

Hegetschweiler Kaspar | Zendy; HausherrPrimo Lorenza | Zendy; Koppenol Willem H. | Zendy; Gramlich Volker | Zendy; Odier Léon | Zendy; Meyer Wolfram | Zendy; Winkler Heiner | Zendy; Trautwein Alfred X. | Zendy

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A Novel Hexanuclear Fe III ‐ cis ‐Inositolato Complex as a Model for Fe III –Polyol Interactions in Aqueous Solution

Author(s) -

Hegetschweiler Kaspar,

HausherrPrimo Lorenza,

Koppenol Willem H.,

Gramlich Volker,

Odier Léon,

Meyer Wolfram,

Winkler Heiner,

Trautwein Alfred X.

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199522421

Subject(s) - aqueous solution , polyhedron , polyol , ion , crystallography , chemistry , simple (philosophy) , inorganic chemistry , stereochemistry , organic chemistry , combinatorics , mathematics , philosophy , epistemology , polyurethane

Corner‐sharing, edge‐sharing, and face‐sharing FeO x polyhedra ( x = 5,6) form a cyclic complex anion in K 5 [OFe 6 {(ino) 6 21H}]·14.5 H 2 O (ino = cis ‐inositol), the first structurally characterized polyolato(oxo)ferrate from aqueous solution. The synthesis is as simple as the structure is complicated (see diagram).

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