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A Novel Hexanuclear Fe III ‐ cis ‐Inositolato Complex as a Model for Fe III –Polyol Interactions in Aqueous Solution
Author(s) -
Hegetschweiler Kaspar,
HausherrPrimo Lorenza,
Koppenol Willem H.,
Gramlich Volker,
Odier Léon,
Meyer Wolfram,
Winkler Heiner,
Trautwein Alfred X.
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199522421
Subject(s) - aqueous solution , polyhedron , polyol , ion , crystallography , chemistry , simple (philosophy) , inorganic chemistry , stereochemistry , organic chemistry , combinatorics , mathematics , philosophy , epistemology , polyurethane
Corner‐sharing, edge‐sharing, and face‐sharing FeO x polyhedra ( x = 5,6) form a cyclic complex anion in K 5 [OFe 6 {(ino) 6 21H}]·14.5 H 2 O (ino = cis ‐inositol), the first structurally characterized polyolato(oxo)ferrate from aqueous solution. The synthesis is as simple as the structure is complicated (see diagram).