Control of the Reactivity of Double Bonds through Their Fixed Geometrical Arrangement | Zendy

Wolff J. Jens | Zendy

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Control of the Reactivity of Double Bonds through Their Fixed Geometrical Arrangement

Author(s) -

Wolff J. Jens

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199522251

Subject(s) - cycloaddition , reactivity (psychology) , orientation (vector space) , double bond , control (management) , bond , chemistry , computational chemistry , crystallography , materials science , mathematics , computer science , polymer chemistry , geometry , organic chemistry , catalysis , business , medicine , alternative medicine , finance , pathology , artificial intelligence

Reactions may proceed selectively if the reactants are arranged in a defined geometrical orientation with respect to each other. Recent success in the application of this concept pertaining to the [2+2]cycloaddition of two preorganized double bonds (shown on the right) is presented.

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