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Transition Metal Catalyzed Synthesis of Seven‐Membered Carbocyclic Rings
Author(s) -
Dyker Gerald
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199522231
Subject(s) - rhodium , catalysis , transition metal , ring (chemistry) , component (thermodynamics) , chemistry , stereochemistry , key (lock) , organic chemistry , physics , computer science , thermodynamics , computer security
A variant of the Diels‐Alder reaction with a vinylcyclopropane group as “homodiene” component enables a novel access to seven‐membered carbocyclic rings [Eq. (a)]. Metallacycles are considered as key intermediates of this rhodium‐catalyzed process.