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Radical CC Bond Formation by Photoinduced Electron Transfer Addition of α‐Silyl Carbamates to Acceptor‐Substituted Alkenes
Author(s) -
Meggers Eric,
Steckhan Eberhard,
Blechert Siegfried
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199521371
Subject(s) - silylation , chemistry , radical , trimethylsilyl , photochemistry , acceptor , electron acceptor , fragmentation (computing) , electron transfer , medicinal chemistry , organic chemistry , catalysis , computer science , operating system , physics , condensed matter physics
α‐Silyl carbamates are suitable precursors for carbon radicals. The silyl group is cleaved by photosensitized oxidative fragmentation, and the resulting radicals can add to alkenes. Equation (a) shows one example. A = acceptor, Tms = trimethylsilyl.