[Mo 154 (NO) 14 O 420 (OH) 28 (H 2 O) 70 ] (25 ± 5)− : A Water‐Soluble Big Wheel with More than 700 Atoms and a Relative Molecular Mass of About 24000 | Zendy

Müller Achim | Zendy; Krickemeyer Erich | Zendy; Meyer Jochen | Zendy; Bögge Hartmut | Zendy; Peters Frank | Zendy; Plass Winfried | Zendy; Diemann Ekkehard | Zendy; Dillinger Stephan | Zendy; nenbruch Fritz | Zendy; Randerath Markus | Zendy; Menke Carsten | Zendy

Premium

[Mo 154 (NO) 14 O 420 (OH) 28 (H 2 O) 70 ] (25 ± 5)− : A Water‐Soluble Big Wheel with More than 700 Atoms and a Relative Molecular Mass of About 24000

Author(s) -

Müller Achim,

Krickemeyer Erich,

Meyer Jochen,

Bögge Hartmut,

Peters Frank,

Plass Winfried,

Diemann Ekkehard,

Dillinger Stephan,

nenbruch Fritz,

Randerath Markus,

Menke Carsten

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199521221

Subject(s) - molybdate , cluster (spacecraft) , ion , crystallography , analytical chemistry (journal) , chemistry , electron , materials science , mineralogy , physics , inorganic chemistry , nuclear physics , organic chemistry , computer science , programming language , chromatography

Complex clusters the size of small proteins can be generated in reduced molybdate solutions by linking defined fragments. An example of this is the giant cluster (NH 4 ) 25±5 [Mo 154 (NO) 14 O 420 (OH) 28 (H 2 O) 70 ]·ca. 350 H 2 O with a molar mass of more than 30000 gmol −1 , the anion of which is shaped like a tire with a nanodimensional cavity more than 20 Å in diameter and has an extremely large inner and outer surface as well as a large number of mobile electrons.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research