From  cyclo ‐Te 8  to Te       x    n  −     Sheets: Are Nonclassical Polytellurides More Classical than We Thought? | Zendy

Kanatzidis Mercouri G. | Zendy

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From cyclo ‐Te 8 to Te x n − Sheets: Are Nonclassical Polytellurides More Classical than We Thought?

Author(s) -

Kanatzidis Mercouri G.

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199521091

Subject(s) - counterion , planar , chemistry , template , structural chemistry , solid state , crystallography , nanotechnology , materials science , chemical physics , ion , organic chemistry , computer science , computer graphics (images)

The importance of exploratory synthesis in advancing inorganic chemistry is exemplified by the interesting results that have been obtained in polychalcogenide chemistry. Thus, for example, Te 8 rings and planar [Te 6 ] n 3 n −layers have been found in the solid‐state structure of Cs 3 Te 22 [ Angew. Chem. 1995 , 107 , 450]. The counterions, which appear to function as templates, strongly influence the formation and structure of the products. Is this a route to polychalcogenides with defined structural features and material properties?

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