An Alkylperoxoiron( III ) Intermediate and Its Role in the Oxidation of Aliphatic CH Bonds | Zendy

Kim Jinheung | Zendy; Larka Edmund | Zendy; Wilkinson Elizabeth C. | Zendy; Que Lawrence | Zendy

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An Alkylperoxoiron( III ) Intermediate and Its Role in the Oxidation of Aliphatic CH Bonds

Author(s) -

Kim Jinheung,

Larka Edmund,

Wilkinson Elizabeth C.,

Que Lawrence

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199520481

Subject(s) - amine gas treating , chemistry , decomposition , raman spectroscopy , electron paramagnetic resonance , tris , medicinal chemistry , alcohol , oxidation state , redox , kinetics , photochemistry , polymer chemistry , catalysis , organic chemistry , nuclear magnetic resonance , biochemistry , quantum mechanics , physics , optics

Based on EPR, Raman, and mass spectral evidence , the formula 1 best describes the transient intermediate which forms upon treatment of 2 with tert ‐butyl hydroperoxide in the presence of alcohol. Kinetic evidence suggests that its decomposition by oxidation of the bound alcohol proceeds via the transition state 3 . tpa = tris(2‐pyridylmethyl)amine.

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