A Molybdenum–Phosphorus Triple Bond: Synthesis, Structure, and Reactivity of the Terminal Phosphido (P 3− ) Complex [Mo(P)(NRAr) 3 ] | Zendy

Laplaza Catalina E. | Zendy; Davis William M. | Zendy; Cummins Christopher C. | Zendy

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A Molybdenum–Phosphorus Triple Bond: Synthesis, Structure, and Reactivity of the Terminal Phosphido (P 3− ) Complex [Mo(P)(NRAr) 3 ]

Author(s) -

Laplaza Catalina E.,

Davis William M.,

Cummins Christopher C.

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199520421

Subject(s) - molybdenum , ligand (biochemistry) , chemistry , reactivity (psychology) , phosphorus , triple bond , sulfur , monomer , crystal structure , crystallography , azide , inorganic chemistry , polymer chemistry , double bond , organic chemistry , polymer , receptor , medicine , biochemistry , alternative medicine , pathology

Molybdenum complex 1 and white phosphorus react smoothly at 28°C to give 2 with a terminal phosphido (P 3− ) ligand. The crystal structure of 2 reveals a monomer with a Mo–P triple bond (2.119(4) Å). Treatment of 2 with mesityl azide gives a complex with a terminal iminophosphenium (PNR + ) ligand; treatment with elemental sulfur leads to a phosphorus monosulfide (PS) complex, R = C(CD 3 ) 2 CH 3 , Ar = 3,5‐C 6 H 3 Me 2 .

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