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Fluxionality Induced by High Pressure: [9‐D]9‐Homocubyl Triflate, a Pressure‐Sensing Molecule
Author(s) -
Spitz Urs. P.,
Eaton Philip E.
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199520301
Subject(s) - trifluoromethanesulfonate , decomposition , high pressure , molecule , chemistry , materials science , thermodynamics , organic chemistry , physics , catalysis
Much better than high temperature , which causes decomposition, high pressure accelerates the automerization (resembling a “molecular gear”) of homocubyl triflate 1 [Eq. (a)] as lebeling studies with [9‐D]‐ 1 showed.