Novel Networks of Unusually Coordinated Silver( I ) Cations: The Wafer‐Like Structure of [Ag(pyz) 2 ][Ag 2 (pyz) 5 ](PF 6 ) 3 ·2G and the Simple Cubic Frame of [Ag(pyz) 3 ](SbF 6 ) | Zendy

Carlucci Lucia | Zendy; Ciani Gianfranco | Zendy; Proserpio Davide M. | Zendy; Sironi Angelo | Zendy

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Novel Networks of Unusually Coordinated Silver( I ) Cations: The Wafer‐Like Structure of [Ag(pyz) 2 ][Ag 2 (pyz) 5 ](PF 6 ) 3 ·2G and the Simple Cubic Frame of [Ag(pyz) 3 ](SbF 6 )

Author(s) -

Carlucci Lucia,

Ciani Gianfranco,

Proserpio Davide M.,

Sironi Angelo

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199518951

Subject(s) - derivative (finance) , crystallography , chemistry , catenation , pyrazine , crystal structure , type (biology) , simple (philosophy) , stacking , stereochemistry , organic chemistry , ecology , philosophy , epistemology , financial economics , economics , biology , dna , biochemistry

The silver salts AgPF 6 and AgSbF 6 react with pyrazine to give unprecedented networks of two‐ and three‐dimensional cubic units. The PF 6 −derivative has a layered structure, whereas the SbF 6 −derivative (shown schematically on the right) contains a simple cubic frame of the α‐polonium type.

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