A New Quantitative Description of the Distance Dependence of Through‐Space  19 F,  19 F Spin–Spin Coupling | Zendy

Ernst Ludger | Zendy; Ibrom Kerstin | Zendy

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A New Quantitative Description of the Distance Dependence of Through‐Space 19 F, 19 F Spin–Spin Coupling

Author(s) -

Ernst Ludger,

Ibrom Kerstin

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199518811

Subject(s) - spin (aerodynamics) , coupling (piping) , space (punctuation) , bridge (graph theory) , condensed matter physics , series (stratigraphy) , materials science , physics , computer science , biology , thermodynamics , paleontology , anatomy , metallurgy , operating system

Fine tuning of the nonbonding FF distances , by bridge length variation and suitable substituents, in a series of difluorometa‐ ( 1 ) and ‐paracyclophanes led to a new quantitative description of distance‐dependent 19 F, 19 F through‐space spin–spin coupling. This will be useful for structural studies of di‐ and oligofluorinated compounds in solution.

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