The [Zr 6 X 18 H 5 ] 3−  Ions with X = Cl, Br, and Related Species | Zendy

Chen Linfeng | Zendy; Cotton F. Albert | Zendy; Wojtczak William A. | Zendy

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The [Zr 6 X 18 H 5 ] 3− Ions with X = Cl, Br, and Related Species

Author(s) -

Chen Linfeng,

Cotton F. Albert,

Wojtczak William A.

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199518771

Subject(s) - octahedron , halide , hydride , crystallography , ion , cluster (spacecraft) , zirconium , chemistry , hydrogen , inorganic chemistry , crystal structure , organic chemistry , computer science , programming language

A new class of octahedral zirconium cluster compounds containing only halide and hydride ligands is described. These contain the anions [Zr 6 X 18 H 4 ] 4− or [Zr 6 X 18 H 5 ] 3− (shown on the right). The hydrogen atoms are randomly disordered on positions in or very near to the centers of all the triangular faces of the Zr 6 octahedron according to X‐ray crystallography.

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