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The Preparation of Salts of [Pd 2 (μ‐Se 2 N 2 )Cl 6 ] 2− , the First Adducts of Diselenium Dinitride
Author(s) -
Kelly Paul F.,
Slawin Alexandra M. Z.
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199517581
Subject(s) - adduct , chemistry , explosive material , ring (chemistry) , medicinal chemistry , polymer chemistry , organic chemistry
An Se 2 N 2 ring bridges two PdCl 3 units (structure shown on the right) in the title compounds, which are formed in the reaction of appropriate salts of [Pd 2 Cl 6 ] 2− with Se 4 N 4 . Unlike Se 4 N 4 , these Se 2 N 2 adducts are not explosive.