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Diodelike Current–Voltage Curves for a Single Molecule–Tunneling Spectroscopy with Submolecular Resolution of an Alkylated, peri ‐Condensed Hexabenzocoronene
Author(s) -
Stabel Andreas,
Herwig Peter,
Müllen Klaus,
Rabe Jürgen P.
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199516091
Subject(s) - quantum tunnelling , molecule , scanning tunneling microscope , spectroscopy , diode , resolution (logic) , chemistry , scanning tunneling spectroscopy , current (fluid) , electrode , materials science , molecular physics , crystallography , optoelectronics , nanotechnology , physics , organic chemistry , quantum mechanics , artificial intelligence , computer science , thermodynamics
The electronic properties of molecules can in some cases be elucidated by scanning tunneling microscopy and spectroscopy. The current–voltage characteristics through the aromatic core of a benzocoronene molecule ( 1 ), localized with submolecular resolution, are the same those of a diode, and are caused by the properties of a single molecule in contact with two electrodes. R = n ‐C 12 H 25 .

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