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Synthesis and X‐Ray Powder Structure of a Novel Porous Uranyl Phenylphosphonate Containing Unidimensional Channels Flanked by Hydrophobic Regions
Author(s) -
Poojary Damodara M.,
Grohol Daniel,
Clearfield Abraham
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199515081
Subject(s) - stacking , uranyl , powder diffraction , crystallography , chemistry , porosity , diffraction , ion , organic chemistry , physics , optics
Stacking interactions between phenyl groups hold the unidimensional channels in the structure of 1 together (shown on the right). The structure was determined from X‐ray powder diffraction data, which revealed that the channel opening is more than 12 Å and the free space approximately 7 Å in diameter.
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