Synthesis and Structure of the First Sulfur‐Bridged [1]Ferrocenophane | Zendy

Pudelski John K. | Zendy; Gates Derek P. | Zendy; Rulkens Ron | Zendy; Lough Alan J. | Zendy; Manners Ian | Zendy

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Synthesis and Structure of the First Sulfur‐Bridged [1]Ferrocenophane

Author(s) -

Pudelski John K.,

Gates Derek P.,

Rulkens Ron,

Lough Alan J.,

Manners Ian

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199515061

Subject(s) - cyclopentadienyl complex , sulfur , crystallography , bridging (networking) , tilt (camera) , crystal structure , chemistry , stereochemistry , geometry , mathematics , organic chemistry , computer science , catalysis , computer network

A sulfur atom is the smallest bridging element yet incorporated into a [1]ferrocenophane. This is demonstrated by the synthesis of the purple, crystalline [1]ferrocenophane 1 (structure depicted on the right). The 31.05(10)° tilt angle between the planes of the cyclopentadienyl rings is the largest for any iron group [ n ]metallocenophane.

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