C  3 ‐Symmetric Hexakis(trimethylsilyl)[7]phenylene[“Tris(biphenylenocyclobutadieno)cyclohexatriene”], a Polycyclic Benzenoid Hydrocarbon with Slightly Curved Topology | Zendy

Boese Roland | Zendy; Matzger Adam J. | Zendy; Mohler Debra L. | Zendy; Vollhardt K. Peter C. | Zendy

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C 3 ‐Symmetric Hexakis(trimethylsilyl)[7]phenylene[“Tris(biphenylenocyclobutadieno)cyclohexatriene”], a Polycyclic Benzenoid Hydrocarbon with Slightly Curved Topology

Author(s) -

Boese Roland,

Matzger Adam J.,

Mohler Debra L.,

Vollhardt K. Peter C.

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199514781

Subject(s) - phenylene , trimethylsilyl , benzene , molecule , trigonal crystal system , topology (electrical circuits) , tris , planar , chemistry , hydrocarbon , crystallography , yield (engineering) , unit (ring theory) , materials science , medicinal chemistry , organic chemistry , combinatorics , mathematics , computer science , crystal structure , polymer , composite material , biochemistry , computer graphics (images) , mathematics education

In four steps and a yield of 14% , the [7]phenylene 1 has been prepared from hexakis(trimethylsilylethynyl)‐benzene. The trigonal 1 is not planar but slightly curved, and the unit cell features two molecules, staggered and offset, facing each other in a concave–concave arrangement.

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