Enhancement of Catalytic Activity for Hydroformylation of Methyl Acrylate by Using Biphasic and “Supported Aqueous Phase” Systems | Zendy

Fremy Georges | Zendy; Monflier Eric | Zendy; Carpentier JeanFrançois | Zendy; Castanet Yves | Zendy; Mortreux André | Zendy

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Enhancement of Catalytic Activity for Hydroformylation of Methyl Acrylate by Using Biphasic and “Supported Aqueous Phase” Systems

Author(s) -

Fremy Georges,

Monflier Eric,

Carpentier JeanFrançois,

Castanet Yves,

Mortreux André

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199514741

Subject(s) - hydroformylation , rhodium , methyl acrylate , catalysis , homogeneous , aqueous solution , chemistry , acrylate , phase (matter) , aqueous two phase system , organic chemistry , homogeneous catalysis , polymer chemistry , polymer , copolymer , physics , thermodynamics

High activities and selectivities are obtained for the rhodium‐catalyzed hydroformylation of methyl acrylate in biphasic and “supported aqueous phase” (SAP) systems [Eq. (a)]. The biphasic system Rh/P(C 6 H 4 SO 3 Na) 3 1 is twice as active as the classic Rh/PPh 3 combination (homogeneous system), and the SAP system Rh/P(C 6 H 4 SO 3 Na) 3 /SiO 2 2 is twenty times more active.

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