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The Two‐Dimensional Network Structure and Metamagnetic Properties of the 2:1 Complex of [Mn(3‐MeOsalen)(H 2 O)]ClO 4 and K 3 [Fe(CN) 6 ]
Author(s) -
Miyasaka Hitoshi,
Matsumoto Naohide,
Ōkawa Hisashi,
Re Nazzareno,
Gallo Emma,
Floriani Carlo
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199514461
Subject(s) - metamagnetism , antiferromagnetism , ferromagnetism , van der waals force , crystallography , coupling (piping) , materials science , chemistry , condensed matter physics , physics , molecule , magnetization , magnetic field , metallurgy , organic chemistry , quantum mechanics
Cyclic tetrameric units (··Mn‐NC‐Fe‐CN··) 4 (depicted on the right) construct the two‐dimensional network of the title compound. The layers thus formed are linked together by van der Waals contacts. The compound displays metamagnetism: ferromagnetic coupling is observed within layers and antiferromagnetic coupling between layers.