The Two‐Dimensional Network Structure and Metamagnetic Properties of the 2:1 Complex of [Mn(3‐MeOsalen)(H 2 O)]ClO 4  and K 3 [Fe(CN) 6 ] | Zendy

Miyasaka Hitoshi | Zendy; Matsumoto Naohide | Zendy; Ōkawa Hisashi | Zendy; Re Nazzareno | Zendy; Gallo Emma | Zendy; Floriani Carlo | Zendy

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The Two‐Dimensional Network Structure and Metamagnetic Properties of the 2:1 Complex of [Mn(3‐MeOsalen)(H 2 O)]ClO 4 and K 3 [Fe(CN) 6 ]

Author(s) -

Miyasaka Hitoshi,

Matsumoto Naohide,

Ōkawa Hisashi,

Re Nazzareno,

Gallo Emma,

Floriani Carlo

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199514461

Subject(s) - metamagnetism , antiferromagnetism , ferromagnetism , van der waals force , crystallography , coupling (piping) , materials science , chemistry , condensed matter physics , physics , molecule , magnetization , magnetic field , metallurgy , organic chemistry , quantum mechanics

Cyclic tetrameric units (··Mn‐NC‐Fe‐CN··) 4 (depicted on the right) construct the two‐dimensional network of the title compound. The layers thus formed are linked together by van der Waals contacts. The compound displays metamagnetism: ferromagnetic coupling is observed within layers and antiferromagnetic coupling between layers.

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