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Silacyclopropene: Generation by High‐Vacuum Flash Pyrolysis and Matrix‐Spectroscopic Identification
Author(s) -
Maier Günther,
Pacl Harald,
Reisenauer Hans Peter
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199514391
Subject(s) - flash vacuum pyrolysis , trimethylsilane , pyrolytic carbon , flash (photography) , pyrolysis , identification (biology) , matrix (chemical analysis) , materials science , combinatorial chemistry , computer science , chemistry , organic chemistry , physics , optics , composite material , botany , biology
Since the first synthesis of a silacyclopropene , efforts have been made to prepare the unsubstituted parent compound 3 . This goal has finally been achieved: Pyrolytic elimination of trimethylsilane from 1 initially leads to the silanediyl 2 , which cyclizes to 3 .
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