[WL(NO)(O)(CH 3 )]— An Unusual Nitrosyltungsten Complex | Zendy

Böhmer Jochen | Zendy; Wieghardt Karl | Zendy; Nuber Bernhard | Zendy

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[WL(NO)(O)(CH 3 )]— An Unusual Nitrosyltungsten Complex

Author(s) -

Böhmer Jochen,

Wieghardt Karl,

Nuber Bernhard

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199514351

Subject(s) - chemistry , wavenumber , metal , atom (system on chip) , crystallography , acceptor , stereochemistry , physics , organic chemistry , optics , computer science , embedded system , condensed matter physics

A strong π acceptor and a strong π donor —NO and O ligands, respectively—coordinated cis to the same metal atom are present in the complex 1 . The NO stretching frequency of the linear WNO unit occurs at extremely low wavenumber (1433 cm −1 ). The red complex 1 forms by reduction of [WL(CO) 2 (NO)] + to [WL(NO)(CO)(Me)] (L = heterocycle) followed by reaction with O 2 .

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