S(NPMe 3 )       4    2+    : The First Structure Determination of a Dication of Hexavalent Sulfur | Zendy

Folkerts Hella | Zendy; Hiller Wolfgang | Zendy; Herker Martin | Zendy; Vyboishchikov Sergei F. | Zendy; Frenking Gernot | Zendy; Dehnicke Kurt | Zendy

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S(NPMe 3 ) 4 2+ : The First Structure Determination of a Dication of Hexavalent Sulfur

Author(s) -

Folkerts Hella,

Hiller Wolfgang,

Herker Martin,

Vyboishchikov Sergei F.,

Frenking Gernot,

Dehnicke Kurt

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199513621

Subject(s) - phosphorane , dication , chemistry , ab initio , covalent bond , acetonitrile , sulfur , crystallography , imine , computational chemistry , polar , stereochemistry , organic chemistry , molecule , physics , catalysis , astronomy

Attraction of the charges on the participant atoms causes the polar covalent NS and NP single bonds in the cation of the phosphorane iminato complex [S(NPMe 3 ) 4 ]Cl 2 (shown on the right) to approach the lengths of double bonds. This is in agreement with the results of ab initio calculations. The complex was obtained from S 2 Cl 2 and the silylated phosphorane imine Me 3 SiNPMe 3 in acetonitrile.

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