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Enantiomerically Pure Palladacycles Derived from β‐Ketosulfoxides
Author(s) -
GarcíaRuano José L.,
González Ana M.,
LópezSolera Isabel,
Masaguer José R.,
NavarroRanninger Carmen,
Raithby Paul R.,
Rodríguez Jesús H.
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199513511
Subject(s) - palladium , sulfoxide , covalent bond , chemistry , section (typography) , stereochemistry , organic chemistry , catalysis , computer science , operating system
A trimeric palladium complex results from the reaction of Pd(OAc) 2 and the sulfoxide 1 . A section of the structure of this complex, which is obtained enantiomerically pure in the ( R,R ) form and contains two dative and two covalent bonds to palladium, is shown at the bottom on the right.