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Bis(hypersilyl)tin and Bis(hypersilyl)lead, Two Electron‐Rich Carbene Homologs
Author(s) -
Klinkhammer Karl Wihelm,
Schwarz Wolfgang
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199513341
Subject(s) - tin , carbene , lead (geology) , electron , chemistry , materials science , physics , organic chemistry , biology , catalysis , paleontology , quantum mechanics
A strongly twisted distannene (shown on the right) is found in crystals of bis(hypersilyl)tin 1 . In its violetbrown solutions 1 is mainly monomeric, as is the blue bis(hypersilyl)lead 2 .
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