η 5 :η 2  Coordination of a  cyclo ‐E 5  Ligand, EP, As | Zendy

Detzel Michaela | Zendy; Friedrich Gabriele | Zendy; Scherer Otto J. | Zendy; Wolmershäuser Gotthelf | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

η 5 :η 2 Coordination of a cyclo ‐E 5 Ligand, EP, As

Author(s) -

Detzel Michaela,

Friedrich Gabriele,

Scherer Otto J.,

Wolmershäuser Gotthelf

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199513211

Subject(s) - iridium , rhodium , chemistry , valence (chemistry) , ligand (biochemistry) , coordination complex , metal , crystallography , valence electron , stereochemistry , electron , coordination number , group 2 organometallic chemistry , ion , molecule , physics , organic chemistry , nuclear physics , biochemistry , receptor , catalysis

An unusual, additional side‐on coordination of an iridium center and a rhodium complex fragment with 16 valence electrons is realized in the new compounds 1 . Compounds 1a , E = P, M = Ir, and 1b , E = As, M = Rh, were prepared from the sandwich complexes [Cp * Fe(η 5 ‐E 5 )]. The isomers of 1a and 1b with terminal η 1 coordination of the metal complex fragment have been obtained as well.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research