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Phosphorane Iminato Complexes of Manganese and Cobalt with Heterocubane Structure
Author(s) -
Mai HansJoachim,
zu Köcker Rolf Meyer,
Wocadlo Sigrid,
Massa Werner,
Dehnicke Kurt
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199512351
Subject(s) - anhydrous , manganese , phosphorane , cobalt , chemistry , crystallography , medicinal chemistry , inorganic chemistry , organic chemistry
Mn 4 N 4 and Co 4 N 4 cubes with almost square faces are found in the title compounds 1 and 2 . They were obtained by the melt reaction of the anhydrous dihalides MnI 2 and CoCl 2 , and Me 3 SiNPEt 3 . Complexes 1 and 2 are the first phosphorane iminato complexes of manganese( II ) and cobalt( II ) with heterocubane structure.
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