Reactions of Carbocations with π Nucleophiles: Polar Mechanism and No Outer Sphere Electron Transfer | Zendy

Patz Matthias | Zendy; Mayr Herbert | Zendy; Maruta Junichi | Zendy; Fukuzumi Shunichi | Zendy

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Reactions of Carbocations with π Nucleophiles: Polar Mechanism and No Outer Sphere Electron Transfer

Author(s) -

Patz Matthias,

Mayr Herbert,

Maruta Junichi,

Fukuzumi Shunichi

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199512251

Subject(s) - carbocation , electron transfer , chemistry , nucleophile , electron , reaction rate constant , photochemistry , proton coupled electron transfer , polar , chemical physics , computational chemistry , kinetics , organic chemistry , physics , classical mechanics , nuclear physics , quantum mechanics , catalysis

Rate constants at least eight orders of magnitude greater than those calculated for the single electron transfer (SET) process are observed for the addition of R + to π‐electron systems. Thus it is clear that in these reactions radical intermediates are generally not found, but that charge transfer is associated with the formation of the new CC σ bond.

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