∞    3    [(CoCp 2 ) ⊂ Fe(μ‐CNSnMe 3 NC) 3 ]: A Purely Organometallic Channel Inclusion Compound | Zendy

Schwarz Peter | Zendy; Siebel Eric | Zendy; Fischer R. Dieter | Zendy; Apperley David C. | Zendy; Davies Nicola A. | Zendy; Harris Robin K. | Zendy

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∞ 3 [(CoCp 2 ) ⊂ Fe(μ‐CNSnMe 3 NC) 3 ]: A Purely Organometallic Channel Inclusion Compound

Author(s) -

Schwarz Peter,

Siebel Eric,

Fischer R. Dieter,

Apperley David C.,

Davies Nicola A.,

Harris Robin K.

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199511971

Subject(s) - inclusion (mineral) , ion , crystallography , group 2 organometallic chemistry , channel (broadcasting) , chemistry , spectroscopy , nuclear magnetic resonance spectroscopy , stereochemistry , materials science , physics , molecule , computer science , mineralogy , organic chemistry , telecommunications , quantum mechanics

Only every second channel of the novel host–guest compound 1 is occupied by stacks of cobaltocenium ions (see picture on the right). The channel inclusion compound is formed by spontaneous self‐assembly of [CoCp 2 ] + , Me 3 Sn + , and [Fe(CN) 6 ] 4− ions in H 2 O. The combination of X‐ray crystallography and multinucleus CP/MAS NMR spectroscopy gave optimal insights into the static and dynamic behavior.

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