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∞ 3 [(CoCp 2 ) ⊂ Fe(μ‐CNSnMe 3 NC) 3 ]: A Purely Organometallic Channel Inclusion Compound
Author(s) -
Schwarz Peter,
Siebel Eric,
Fischer R. Dieter,
Apperley David C.,
Davies Nicola A.,
Harris Robin K.
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199511971
Subject(s) - inclusion (mineral) , ion , crystallography , group 2 organometallic chemistry , channel (broadcasting) , chemistry , spectroscopy , nuclear magnetic resonance spectroscopy , stereochemistry , materials science , physics , molecule , computer science , mineralogy , organic chemistry , telecommunications , quantum mechanics
Only every second channel of the novel host–guest compound 1 is occupied by stacks of cobaltocenium ions (see picture on the right). The channel inclusion compound is formed by spontaneous self‐assembly of [CoCp 2 ] + , Me 3 Sn + , and [Fe(CN) 6 ] 4− ions in H 2 O. The combination of X‐ray crystallography and multinucleus CP/MAS NMR spectroscopy gave optimal insights into the static and dynamic behavior.