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Synthesis, Structure, and Properties of Dinuclear and Trinuclear Rack‐Type Ru II Complexes
Author(s) -
Hanan Garry S.,
Arana Claudia R.,
Lehn JeanMarie,
Fenske Dieter
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199511221
Subject(s) - rack , denticity , chemistry , metal , crystallography , bridging (networking) , bridging ligand , ligand (biochemistry) , stereochemistry , redox , ruthenium , crystal structure , inorganic chemistry , receptor , catalysis , organic chemistry , computer science , computer network , biochemistry , political science , law
Linear arrangements of metal centers fixed by polydentate bridging ligands are found in new Ru II complexes. In the redox‐active complex 1 (X = H, 9‐anthryl), which resmbles a rack, the metal centers can communicate through the bridging ligand.