Binding of Boron and Alkali Metal Cations by a Pseudocryptand | Zendy

Graf Ernest | Zendy; Hosseini Mir Wais | Zendy; Ruppert Romain | Zendy; Kyritsakas Nathalie | Zendy; De Cian André | Zendy; Fischer Jean | Zendy; Estournès Christine | Zendy; Taulelle Francis | Zendy

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Binding of Boron and Alkali Metal Cations by a Pseudocryptand

Author(s) -

Graf Ernest,

Hosseini Mir Wais,

Ruppert Romain,

Kyritsakas Nathalie,

De Cian André,

Fischer Jean,

Estournès Christine,

Taulelle Francis

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199511151

Subject(s) - alkali metal , moiety , chemistry , boron , potassium , selectivity , inorganic chemistry , metal , combinatorial chemistry , stereochemistry , organic chemistry , catalysis

A synthetic analogue of the natural antibiotic boromycin is described. The negatively charged pseudocryptand 1 possessing a spiroborate moiety binds the potassium cation with the highest stability thus far observed with synthetic receptors. Furthermore, compound 1 displays high selectivity for potassium over other alkali metal cations.

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