Complexation of [ N,N ′‐Bis(salicylidene)‐ethylenediiminato]cobalt( III ) +  by Anilines in Dimethylformamide | Zendy

Speiser Bernd | Zendy; Stahl Hartmut | Zendy

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Complexation of [ N,N ′‐Bis(salicylidene)‐ethylenediiminato]cobalt( III ) + by Anilines in Dimethylformamide

Author(s) -

Speiser Bernd,

Stahl Hartmut

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199510861

Subject(s) - cobalt , adduct , chemistry , cyclic voltammetry , dimethylformamide , spectroscopy , nuclear magnetic resonance spectroscopy , medicinal chemistry , stability constants of complexes , inorganic chemistry , polymer chemistry , stereochemistry , electrochemistry , organic chemistry , electrode , aqueous solution , physics , quantum mechanics , solvent

Possible intermediates in the oxygenation of anilines 1 in the presence of complexes such as 2 are represented by adducts of these components. The formation constants for these complexes (single and double exchange of axial dmf ligands by 1 ) were determined quantitatively by cyclic voltammetry and by 1 H NMR spectroscopy.

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