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Complexation of [ N,N ′‐Bis(salicylidene)‐ethylenediiminato]cobalt( III ) + by Anilines in Dimethylformamide
Author(s) -
Speiser Bernd,
Stahl Hartmut
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199510861
Subject(s) - cobalt , adduct , chemistry , cyclic voltammetry , dimethylformamide , spectroscopy , nuclear magnetic resonance spectroscopy , medicinal chemistry , stability constants of complexes , inorganic chemistry , polymer chemistry , stereochemistry , electrochemistry , organic chemistry , electrode , aqueous solution , physics , quantum mechanics , solvent
Possible intermediates in the oxygenation of anilines 1 in the presence of complexes such as 2 are represented by adducts of these components. The formation constants for these complexes (single and double exchange of axial dmf ligands by 1 ) were determined quantitatively by cyclic voltammetry and by 1 H NMR spectroscopy.