The First Mixed‐Metal Borole Cluster; Stabilization of Formally 14e Pd Centers in the Re 2 Pd 2  Electron‐Deficient [{[(η 5 ‐C 4 H 4 BPh)(CO) 3 Re]Pd} 2 ] Cluster | Zendy

Braunstein Pierre | Zendy; Englert Ulli | Zendy; Herberich Gerhard E. | Zendy; Neuschütz Mark | Zendy

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The First Mixed‐Metal Borole Cluster; Stabilization of Formally 14e Pd Centers in the Re 2 Pd 2 Electron‐Deficient [{[(η 5 ‐C 4 H 4 BPh)(CO) 3 Re]Pd} 2 ] Cluster

Author(s) -

Braunstein Pierre,

Englert Ulli,

Herberich Gerhard E.,

Neuschütz Mark

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199510101

Subject(s) - cluster (spacecraft) , electron , valence (chemistry) , metal , crystallography , planar , electron counting , chemistry , physics , nuclear physics , computer science , computer graphics (images) , organic chemistry , programming language

Borole and cluster chemistry are combined for the first time . The result is the title compound (shown right), a novel, intriguing Re 2 Pd 2 cluster with 54 valence electrons. X‐ray structure analysis of this compound, which forms deep blue‐green crystals, showed that the Re 2 Pd 2 unit is planar.

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