Effective Charge Separation in Intermolecular Complexes of an Electron Donor and a Doubly Branched Triad Assembly: A Model System for Environmental Effects Controlling Electron Transfer | Zendy

Zahavy Eran | Zendy; Seiler Martin | Zendy; MarxTibbon Sharon | Zendy; Joselevich Ernesto | Zendy; Willner Itamar | Zendy; Dürr Heinz | Zendy; O'Connor Donald | Zendy; Harriman Anthony | Zendy

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Effective Charge Separation in Intermolecular Complexes of an Electron Donor and a Doubly Branched Triad Assembly: A Model System for Environmental Effects Controlling Electron Transfer

Author(s) -

Zahavy Eran,

Seiler Martin,

MarxTibbon Sharon,

Joselevich Ernesto,

Willner Itamar,

Dürr Heinz,

O'Connor Donald,

Harriman Anthony

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199510051

Subject(s) - triad (sociology) , intermolecular force , electron transfer , redox , supramolecular chemistry , chemistry , electron , charge (physics) , photochemistry , derivative (finance) , chemical physics , crystallography , molecule , inorganic chemistry , organic chemistry , physics , crystal structure , psychology , quantum mechanics , psychoanalysis , financial economics , economics

Back electron transfer of the redox intermediates generated by irradiation of the supramolecular complex 1 is 10 4 times slower than in the free triad. In 1 , in which a dialkoxybenzene derivative is positioned between two bipyridinium arms of the triad, the distance between the redox centers is greater than in the free Ru II complex.

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