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The First Sulfur( VI )–Nitrogen–Phosphorus Macrocycles
Author(s) -
Ni Yizeng,
Lough Alan J.,
Rheingold Arnold L.,
Manners Ian
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199509981
Subject(s) - sulfur , ring (chemistry) , phosphorus , nitrogen , chemistry , polymerization , crystallography , stereochemistry , organic chemistry , polymer
The by‐products of the thermal ring‐opening polymerization of a six‐membered N 3 P 2 S ring were identified as 12‐, 18‐, 24‐, 30‐, and 36‐membered sulfur( VI )/nitrogen/phosphorus macrocycles. The 24‐membered macrocycle 1 is the largest inorganic ring system that has yet been characterized by X‐ray crystallography.