Tetrakis[bis(trimethylsilyl)methyl]dialuminoxane with a Linear AlOAl Group | Zendy

Uhl Werner | Zendy; Koch Matthias | Zendy; Hiller Wolfgang | Zendy; Heckel Maximilian | Zendy

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Tetrakis[bis(trimethylsilyl)methyl]dialuminoxane with a Linear AlOAl Group

Author(s) -

Uhl Werner,

Koch Matthias,

Hiller Wolfgang,

Heckel Maximilian

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199509891

Subject(s) - steric effects , trimethylsilyl , chemistry , derivative (finance) , group (periodic table) , monomer , oxygen atom , crystallography , oxygen , crystal structure , atom (system on chip) , aluminium , stereochemistry , medicinal chemistry , molecule , organic chemistry , polymer , computer science , financial economics , economics , embedded system

A monomeric dialuminoxane with a linear AlOAl group and a planer C 2 AlOAlC 2 framework is a description of the title compound 1 . Four bulky substituents provide strong steric protection. Dialuminoxane 1 arises by insertion of an oxygen atom into the AlAl bond of the corresponding dialuminum derivative. Crystal structure data and NMR spectra suggest a π interaction between aluminum and oxygen.

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