Complexes with Polar WW Multiple Bonds: [W 2 (O i Pr) 4 L(dmpe) 2 ] (L = (H) 2 , CO) and [W 2 (O) 4 (μ‐O){W(CO)(dmpe) 2 } 2 ] | Zendy

Chisholm Malcolm H. | Zendy; Kramer Keith S. | Zendy; Streib William E. | Zendy

Premium

Complexes with Polar WW Multiple Bonds: [W 2 (O i Pr) 4 L(dmpe) 2 ] (L = (H) 2 , CO) and [W 2 (O) 4 (μ‐O){W(CO)(dmpe) 2 } 2 ]

Author(s) -

Chisholm Malcolm H.,

Kramer Keith S.,

Streib William E.

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199508911

Subject(s) - homonuclear molecule , reactivity (psychology) , chemistry , tungsten , crystallography , stereochemistry , medicinal chemistry , molecule , organic chemistry , medicine , alternative medicine , pathology

An unsupported WW multiple bond between centers having different oxidation states is found in the homonuclear complex 1 , which is formed from [W 2 (O i Pr) 4 ( i Bu) 2 ], a complex containing a WW bond. Dimers of this kind with mixed oxidation states arise because tungsten can bind hard as well as soft ligands. Such complexes should display interesting reactivity.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research