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Octadecanuclearity in Manganese Carboxylate Chemistry: K 4 [Mn 18 O 16 (O 2 CPh) 22 (phth) 2 (H 2 O) 4 ] (phthH 2 = phthalic acid)
Author(s) -
Hendrickson David N.,
Aubin Sheila M. J.,
Squire Rachel C.,
Folting Kirsten,
Streib William E.,
Christou George
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199508871
Subject(s) - manganese , carboxylate , chemistry , ion , inorganic chemistry , potassium , crystallography , stereochemistry , organic chemistry
Small change—large effect: If some of the carboxylato ligands in the coordination sphere of the anion in 1 , which contains the butterfly‐like [Mn 4 (μ 3 ‐O) 2 ] unit, are replaced by dicarboxylato ligands by treatment with potassium hydrogen phthalate, the title compound 2 containing an Mn 18 O 16 framework in its anion is formed. It is the largest Mn/O aggregate discovered to date.