Octadecanuclearity in Manganese Carboxylate Chemistry: K 4 [Mn 18 O 16 (O 2 CPh) 22 (phth) 2 (H 2 O) 4 ] (phthH 2  = phthalic acid) | Zendy

Hendrickson David N. | Zendy; Aubin Sheila M. J. | Zendy; Squire Rachel C. | Zendy; Folting Kirsten | Zendy; Streib William E. | Zendy; Christou George | Zendy

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Octadecanuclearity in Manganese Carboxylate Chemistry: K 4 [Mn 18 O 16 (O 2 CPh) 22 (phth) 2 (H 2 O) 4 ] (phthH 2 = phthalic acid)

Author(s) -

Hendrickson David N.,

Aubin Sheila M. J.,

Squire Rachel C.,

Folting Kirsten,

Streib William E.,

Christou George

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199508871

Subject(s) - manganese , carboxylate , chemistry , ion , inorganic chemistry , potassium , crystallography , stereochemistry , organic chemistry

Small change—large effect: If some of the carboxylato ligands in the coordination sphere of the anion in 1 , which contains the butterfly‐like [Mn 4 (μ 3 ‐O) 2 ] unit, are replaced by dicarboxylato ligands by treatment with potassium hydrogen phthalate, the title compound 2 containing an Mn 18 O 16 framework in its anion is formed. It is the largest Mn/O aggregate discovered to date.

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