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Reaction of a Vanadium( III ) Amide with H 2 : Isolation and Characterization of a Polynuclear Mixed‐Valence Polyhydrido–Nitrido Complex
Author(s) -
Berno Pietro,
Gambarotta Sandro
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199508221
Subject(s) - hydrogenolysis , chemistry , vanadium , silanes , amide , ion , valence (chemistry) , bridging (networking) , stereochemistry , catalysis , crystallography , inorganic chemistry , medicinal chemistry , organic chemistry , silane , computer network , computer science
Complex 2 is formed by two discrete ions which originate during hydrogenolysis of 1 according to Equation (a). The cation is dinuclear with three bridging hydrido ligands. The mixed‐valent anion of 2 is also dinuclear and contains two bridging nitrido moieties, which cannot be the product of the hydrogenolysis of NSi bonds since silanes are not formed in the reaction.