Novel “π‐Boat” Cage Compounds as Potential Cryptands | Zendy

Gleiter Rolf | Zendy; Hövermann Kirstin | Zendy; Ritter Joachim | Zendy; Nuber Bernhard | Zendy

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Novel “π‐Boat” Cage Compounds as Potential Cryptands

Author(s) -

Gleiter Rolf,

Hövermann Kirstin,

Ritter Joachim,

Nuber Bernhard

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199507891

Subject(s) - trimer , cryptand , monomer , benzene , dimer , cage , bridge (graph theory) , chemistry , computational chemistry , organic chemistry , polymer , engineering , structural engineering , medicine , ion

Not only aesthetic, but also structurally interesting are the novel bridged π systems like 1 with “π boat” units. They can be synthesized by cyclization of 1,6‐diazacyclodeca‐3,8‐diyne with dihalides. Whether the trimer 1 or a monomer or dimer forms depends on the geometrical properties of the bridge monomers employed (in 1 para ‐substituted benzene).

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