The Reactivity of 1,3‐Butadiyne Moieties in the “Exploding” [ n ]Rotanes—A Crown of Thiophenes | Zendy

Kozhushkov Sergei | Zendy; Haumann Thomas | Zendy; Boese Roland | Zendy; Knieriem Burkhardt | Zendy; Scheib Stefan | Zendy; Bäuerle Peter | Zendy; de Meijere Armin | Zendy

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The Reactivity of 1,3‐Butadiyne Moieties in the “Exploding” [ n ]Rotanes—A Crown of Thiophenes

Author(s) -

Kozhushkov Sergei,

Haumann Thomas,

Boese Roland,

Knieriem Burkhardt,

Scheib Stefan,

Bäuerle Peter,

de Meijere Armin

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199507811

Subject(s) - reactivity (psychology) , crown (dentistry) , chemistry , polymer chemistry , photochemistry , materials science , medicine , alternative medicine , pathology , composite material

Crowns of thiophenes of type 2 with five, six, and eight heterocycles were obtained in moderate to good yields in the reaction of the appropriate [ n ]rotanes of type 1 and Na 2 S. In the crystal 2 adopts a chairlike conformation with three thiophene S atoms above and three below the equatorial plane of the macrocycle.

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