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Modeling the Remote‐Controlled Organization of Particles in a Nanodimensional Cavity: Synthesis and Properties of (Et 3 NH) 3 ( t BuNH 3 ) 2 ‐Na 2 [(H 2 O) 2 ,N − 3 ⊂ V 14 O 22 (OH) 4 (PhPO 3 ) 8 ]· 6H 2 O·2DMF
Author(s) -
Müller Achim,
Hovemeier Kai,
Krickemeyer Erich,
Bögge Hartmut
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199507791
Subject(s) - ion , molecule , chemical physics , nanotechnology , host (biology) , crystallography , physics , chemistry , materials science , organic chemistry , biology , ecology
The arrangement of charged and uncharged guests (N − 3and two H 2 O molecules; see structure on the right) and their interaction in the cavity of the anion of the title compound 1 can be controlled by deliberately exchanging particles in the truncated cone outside the host (not shown), which resembles an ion channel. Since 1 can incorporate a diversity of guests, continuing studies promise exciting insights into these interactions.