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Topochemical Reaction Control in Solution
Author(s) -
Hopf Henning,
Greiving Helmut,
Jones Peter G.,
Bubenitschek Peter
Publication year - 1995
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.199506851
Subject(s) - yield (engineering) , solid state , crystal structure , irradiation , lattice (music) , photochemistry , chemistry , materials science , crystallography , chemical engineering , physics , metallurgy , engineering , nuclear physics , acoustics
The controlling function of the crystal lattice in many reactions in the solid state can be exercised by the rigid [2.2]paracyclophane spacer in photochemical processes in solution. For example, irradiation of the bisvinylogous cinnamophane 1 affords [5]ladderane 2 in good yield.
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