Lanthanoid Complexes with [(dad)Li] Ligands—New Starting Materials for Organolanthanoid Chemistry | Zendy

Görls Helmar | Zendy; Neumüller Bernhard | Zendy; Scholz Annett | Zendy; Scholz Joachim | Zendy

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Lanthanoid Complexes with [(dad)Li] Ligands—New Starting Materials for Organolanthanoid Chemistry

Author(s) -

Görls Helmar,

Neumüller Bernhard,

Scholz Annett,

Scholz Joachim

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199506731

Subject(s) - lanthanide , ionic radius , chemistry , cyclopentadienyl complex , halide , diene , ionic bonding , inorganic chemistry , crystallography , computational chemistry , organic chemistry , ion , catalysis , natural rubber

Easy to synthesize and highly soluble are the new (1,4‐diaza‐1,3‐diene) complexes 1 and 2 , which can be considered as alternative starting materials to the frequently used cyclopentadienyl lanthanoid halides in organolanthanoid chemistry. The similarity of Cp ligands and the [(dad)Li] ‐ unit is apparent in the structure of 1 on the right; complexes 2 have a different structure as a result of the smaller ionic radius of the lanthanoid.

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