A Co 3  Complex Containing a Bent Trimetal Chain, and Other 1,1′‐Ferrocenedithiolato Complexes | Zendy

Herberhold Max | Zendy; Jin GuoXin | Zendy; Rheingold Arnold L. | Zendy

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A Co 3 Complex Containing a Bent Trimetal Chain, and Other 1,1′‐Ferrocenedithiolato Complexes

Author(s) -

Herberhold Max,

Jin GuoXin,

Rheingold Arnold L.

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199506561

Subject(s) - bent molecular geometry , ligand (biochemistry) , triad (sociology) , cobalt , chemistry , chain (unit) , crystallography , stereochemistry , physics , receptor , inorganic chemistry , biochemistry , organic chemistry , psychology , astronomy , psychoanalysis

A versatile ligand system capable of acting as a two‐four‐, and six‐electron ligand in Cp * complexes of the cobalt triad is the bulky 1,1′‐ferrocenedithiolato ligand [S 2 fc]. In the Co 3 complex 1 , [S 2 fc] bridges the CoCo bonds symmetrically and functions as a six‐electron donor. The unusual bent Co 3 chain in 1 has been structurally characterized.

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