A New Method for the Synthesis of Amphipolar Phosphorus‐Containing Heterocycles | Zendy

Karsch Hans H. | Zendy; Witt Eva | Zendy; Schneider Arnold | Zendy; Herdtweck Eberhardt | Zendy; Heckel Maximilian | Zendy

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A New Method for the Synthesis of Amphipolar Phosphorus‐Containing Heterocycles

Author(s) -

Karsch Hans H.,

Witt Eva,

Schneider Arnold,

Herdtweck Eberhardt,

Heckel Maximilian

Publication year - 1995

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.199505571

Subject(s) - ring (chemistry) , chemistry , cascade , cleavage (geology) , bond cleavage , phosphorus , computational chemistry , stereochemistry , combinatorial chemistry , organic chemistry , materials science , catalysis , chromatography , fracture (geology) , composite material

The word amphipolar characterizes the cyclic bonding interaction between alternately oppositely charged atoms that, for example, distinguishes the cyclotriphosphazenes from aromatic six‐membered ring compounds. An example is 1 (“1λ 5 ,3λ 5 ,5λ 5 ‐2λ 3 ‐tetraphosphabenzene”). It has now been synthesized by an new method incorporating a unique cascade of equivalent bond formation and cleavage reactions (PP, PC bonds).

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